Diaqua(trifluoroacetato-κ2 O,O′)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3 N 2,N 1,N 6]manganese(II) trifluoroacetate
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چکیده
The Mn(II) atom in the two independent ion-pairs of the title salt, [Mn(C(2)F(3)O(2))(C(18)H(12)N(6))(H(2)O)(2)]C(2)F(3)O(2), is N,N',N''-chelated by the neutral N-heterocycle and O,O'-chelated by the carboxyl-ate ion, the five atoms involved in chelation comprising a penta-gon around it. The apical sites of the trans-penta-gonal bipyramidal coordination geometry are occupied by two water mol-ecules. The cations and lattice anions are linked by O-H⋯O and O-H⋯N hydrogen bonds into a three-dimensional network.
منابع مشابه
Diacetato-κO;κ2 O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3 N 2,N 1,N 6)manganese(II) monohydrate
The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately penta-gonal-bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water mol-ecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial ...
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